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APPLICATIONS > PROMAXON® AS A THIXOTROPIC ADDITIVE >

   
PROMAXON® as a Thixotropic Additive
   

PROMAXON® D as a Thixotropic Additive in epoxy Resins

        

1. Introduction
PROMAXON® is a calcium silicate hydrate. It is the result of a hydrothermal synthesis where, by means of a special crystallization process and controlled crystal growth, spherical particles are obtained. The open inner structure of these particles is surrounded by an outer shell of close knitted crystals. This unique particle corresponds with the known mineral xonotlite of which the chemical synthesis can be written as: 
6Ca(OH)2 + 6 SiO2 + H2O > 6 CaO SiO2 H2O + 6H20
It appears as a white powder which is commercialized under the trade name PROMAXON®.

 2. Specifications 

SiO2

[%]

49.0

CaO

[%]

42.9

AI2O3

[%]

0.2

Fe2O3

[%]

0.2

  K2O

 [%]

 0,2

Na2O

[%]

0.2

L.o.i.

[%]

6.1

Bulk density

[g/l]

100

Tapped density

[g/l]

160

Av.particle size

[µm]

60

Moisture content

[%]

<3

pH value

[-]

10

Specific surface

[m²/g]

60

Thermal stability

                                [°C]

                    750 (Dehydration)

                                [°C]

                        1540 (Melting)



3. Why PROMAXON®?

PROMAXON® is a very interesting thixotropic agent in epoxy systems because:

- easy to use – less dust
- easy to disperse
- easy for post thixotropizing on site
- no risk for overdispersing
- limited moisture absorption
- heat resistant
- inorganic
-
excellent surface appearance
avorable price/performace ratio
-
excellent stock stability
The performances of PROMAXON® are demonstrated in a number of practical examples, which have been tested in our laboratories.


4. Practical examples


High Filled systems :

SHERING RESIN

Schering resin in an epoxy mortar and filled with quartzflour, PROMAXON® D is evaluated in comparison with pyrogenicsilica. With PROMAXON® D it is clear to see that larger particle size is advantageous for this application

High filled epoxy mortar
Mixture

Europox 776

16.00 %

Eurodur 43

9.60 %

Quartz flour

74.40 %


Thixotropic agent

PROMAXON® D

2.00 %

Pyrog. Silica

7.50 %

anti sag test in U-profiles 11*12 mm addition for non sag

HOECHST

Hoechst – resin in an epoxy mortar. An hydrophobic pyrogenic silica is compared to PROMAXON®. A relatively low concentration is needed to obtain an anti sag situation for PROMAXON®.

High filled mortar

Mixture

Beckopox EP 117                               

50.0 parts

Beckopox hardener 10.0 parts

Quartz flour W2

60.0 parts

Quartz sand 7- 1.2 mm

118.5 parts


Thixotropic agent

PROMAXON® D

4.0 parts

Pyrog. Silica (hydrophobic)

3.0 parts

anti sag test in U-profiles 11*12 mm addition for non sag


Filled Systems:

HOECHST RESIN

Waterbased epoxy coatingHoechst-resin in a waterbased epoxy coating used to paint concrete surfaces. Comparing an addition of 2 pph PROMAXON® D with 1 pph pyrogenic Silica, a higher viscosity level is achieved at lower speed. The STI is increased resulting in a comparable viscosity at higher speed.

Componant A

Beckopox hardener EH 623

136.0 parts

TiO2 RN59

91.0 parts

Iron oxide black

12.5 parts

EWO-weiss normal

76.0 parts

Micro-talc ATI

54.0 parts

additol XW 393

3.5 parts

additol XW 393

1.5 parts

water

50.0 parts

 
Alter dispersion:

isopiopanol

37.5 parts

water

132.0 parts

 
Component B

Beckopox EP 122

91.0 parts

Beckopox VEP 2281

242.0 parts

Water

67.0 parts

 
Ratio A/B: 60/40

Thixotropic agent

PROMAXON® D

pyrog. silica

Comp A

2 pph

1 pph


Brookfield viscosity
Comp A + B

1 rpm

8.000

6.000

10 rpm

1.860

1.500

STI 1/10

4.3

4.0

 


4. Stockability
The stockstability of an epoxy mixture, containing PROMAXON® as thixotropic agent, is measured during a period of 2 to 3 months.
After thixotropising the A components, the mixtures were stored for a certain period of time, whereafter the anti sag effect was determined in U-profiles for the mortars and with the driptest for the coatings.

SIKA CHEMIE
Sika Chemie: Icosit 255, thixotropised with 4,5 pph PROMAXON® D, shows no sag after the two months test period:


Product: Icosit 255 – Sika Chemie - Epoxy coating
Thixotropic agent: PROMAXON® D - 4.5 pph
Anti sag test drip test: 1 mm thick coating on glas sheet

intitial

0 mm

1 day

0 mm

1 week

0 mm

2 weeks

0 mm

1 month

0 mm

2 months

0 mm

 


5. Test Methods
Anti-sag test drip test
In order to compare different thixotropic agents in filled systems, a so called drip test is carried out. Here a coating is applied on a glass sheet, using a filmograph of which the clearance is regulated at 1.35 mm, this in order to obtain a 1 mm layer. Immediately after application the glass sheet + coating is installed vertically and the sag is evaluated after hardening. The result is expressed in parts per hundred (pph), calculated on the entire composition, of the thixotropic agent needed to obtain a non sag situation. When stockstabitlityncerned the value of sagging is noted.

Anti sag test in U-profiles
In the U-profile anti sag test high filled systems for thick layer application are evaluated. The principle is the same test, the result is expressed in pph thixotropic agent needed to obtain a non sag situation. When stockstability is concerned the value of the sagging is noted. Therefore half a U-profile (11*12 mm) is filled with the mixture. This is installed vertically with the empty side below in order to create the possibility to sag down. After hardening the sag is evaluated.



6. General consideration
These examples reveal the PROMAXON® interacts with the pigments or fillers to form a network. This network produces an increased viscosity at low shear, but also prevents settling of these fillers. The network is broken down by shear forces, which results in a low application viscosity. The network structure is quickly reformed when these forces are removed and this prevents the sagging of the applied layer. In high filled systems only small amounts of PROMAXON® need to be added to obtain this effect.
Our results show that PROMAXON® demonstrates a good and rheological stability during hardening. However, the efficiency of PROMAXON® depends upon the whole compsition; the performance and the quantity needed of PROMAXON® must therefore de determined in a case study for each system seperatley.



Download Documents
Application Datasheet Thixotropic additive MSDS
MSDS Sheet PROMAXON D
Technical Datasheet PROMAXON D
ISO 9001 2000
ISO 41001 2004